Atmospheric
problems
I was triggered
into this topic by reading a recent paper in New Scientist on nitrogen
problems. But before I get onto that I would like to spend some space to write
on other problems in the atmosphere. We here so much about CO2 these days that
is easy to forget there are other issues. It is encouraging that some have been
at least partly resolved by international efforts. The carbon issue is so
massive that it would be easy to become discouraged and while other problems
have been smaller they show that solutions are possible.
The first I
want to discuss came to prominence in the mid 20th century. It was
acid rain such that mildly acidic rain was adversely affecting long lived
vegetation such as trees. The cause was exhaust plumes from high chimneys from
such as power stations were pumping sulphur in the form of oxides into the
upper atmosphere where is combined with water in clouds or rain to acidify rain
precipitating many hundreds of miles away. The obvious solution was to remove
sulphur from the fuel. Treatment in the smokestack is possible but expensive.
There is an awareness nowadays of the more local issues and petrol and diesel
fuels are now commonly desulphurised.
The second
issue coming apparent towards the end of the 20th century was ozone
depletion. Ozone is an important part of the upper atmosphere where it blocks
some harmful solar radiation. The ozone loss was caused by chlorofluorocarbons
( CFC’s ) released by such as aerosol
cans and refrigerators. Particular types of CFC were the major problem. CFC’s
were comparatively new ( mid century ) and had properties which were very
desirable in other ways. For example carbon tetrafluoride was an excellent and
widely used cleaning solvent. I was personally very much involved in
researching replacements. An international agreement ( the Montreal Protocol )
was made in 1985 to limit as far as possible the worst chemicals. There was no
single solution for all the applications and many factors such as efficiency
and toxicity had to be taken into account.
As far as atmospheric
carbon is concerned carbon dioxide gets the attention but it isn’t the only
problem. Methane ( CH4 ) is more potent although shorter lived. Methane is a natural
gas and as such is the gas network fuel. The gas network is imperfect and leaks
occur at all the points in the chain of exploration, production, transportation
and use. Methane is a versatile relatively clean fuel and many believe it is an
essential bridge fuel to a low carbon future. When used as a fuel it produces
less CO2 and much less of other contaminants.
Methane is not
just produced as a fossil fuel. Natural decay of organic material also produces
methane. Ruminants particularly cattle also belch and fart methane during their
digestion. This a major source of methane and has led to interest in synthetic
meat and calls for a decrease in meat production.
Nitrogen is the
major component of earths atmosphere, some 79%. Nitrogen is very stable, and is nearly inert as a gas.
However nitrogen is an essential ingredient of all animal and vegetable life.
Legumes( such as peas, beans ) have symbiotic bacteria which take atmospheric
nitrogen and convert it into soluble form which can be used by plants. This is
known as “fixing” nitrogen. Farmers by experience learned to rotate crops so
that the nitrogen fixing ability of legumes was exploited. Nitrogen was
obtained by mining niter and guano on tropical islands. However it was realised that a method of
fixing atmospheric nitrogen would enable crops to be fertilised more
effectively. One of the triumphs of early 20th century chemistry was
the development of the Haber-Bosch process which did precisely that. The
process is very energy intensive but it has enabled a big increase in crop
yields. The New Scientist paper suggests it enables 2 million people not to go
hungry.
The
availability of nitrogen in the form of ammonia ( NH3) enables a range of
fertilisers to be produced Much is in
the form of urea, (NH2)2 CO. Because nitrogen fertiliser is cheap and readily
available it is over used. Some is released as nitrogen oxide a potent
greenhouse gas. There are other issues with fertiliser such as over use. Again
nitrogen oxide is an ozone deletant so acts as discussed above. Also excess
fertiliser is washed from the soil and finds its way into rivers and the sea.
In these waters it fertilises the growth of algae, which depletes the dissolved
oxygen and results in fish death and foul smelling water.
This general
process of algal growth polluting water is known as eutrophication. I was
involved with this issue with another vital fertiliser ingredient, phosphorus.
My interest was the use of phosphates in cleaning products where they are safe,
effective and economical but potentially have this eutrophication problem.
There has been widespread legislative misunderstanding as detergent phosphates
are comparatively minor part of the problem. Phosphorus from agriculture and
other sources ( Including human sewage ) is the major problem.
Incidentally
nitrogen oxides are pollutants formed when motor fuels are burned. The
demonisation of diesels results from their production of more nitrogen oxides
that petrol engines while diesel also produces less CO2. It has been suggested
that nitrogen oxides also aid the production of fine particles of carbon ( soot
) in diesels. Modern diesel engines are modified to avoid this using particle
filters which trap and burn off the particles.
There are two
main approaches to alleviate the nitrogen oxide problem in fertiliser. One is
to apply in more efficient ways using less. The other is research into fixing
nitrogen using more efficient methods than the Haber-Bosch process. Work is
underway to produce symbiotic bacteria which will enable more plant species to
a behave like legumes.
The really
encouraging feature of this history is that international agreement has removed
the ozone depletion problem. Action by industry ensured that acid rain has
stopped being a problem. Vehicle missions are very much an ongoing issue
although a combination of legislative and industry action has seen big
improvements. Given the will the carbon and climate change problem can be
solved.